Document Type

Article

Publication Date

Winter 3-1-2005

Abstract

Copper(I) salts of various anions including thiolates, diethyl dithiocarbamate, diethyl dithiophosphate, trithiocyanurate, 1-cyano-3- methylisothiourea, 2-aminothiazole, and tetrakis(1-imidazolyl)borate are conveniently synthesized by reducing copper(II) sulfate in aqueous ammonia. The addition of phosphine ligands to several of the products is demonstrated, and the crystal structure of [Cu 2 (MBT) 2 (DPPE) 3 ]•Et 2 O (MBT = 2- mercaptobenzothiazole, DPPE = 1,2-bis(diphenylphosphino)ethane) is reported.

Journal Title

Inorganic Chimica Acta

DOI

10.1016/j.ica.2004.11.030

Volume

358

Issue

4

First Page

1331

Creative Commons License

Creative Commons Attribution-Noncommercial-No Derivative Works 4.0 License
This work is licensed under a Creative Commons Attribution-Noncommercial-No Derivative Works 4.0 License.

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