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Azidotetrakis(trimethylphosphine)nickel(II) Tetrafluoroborate

Carson, Caryn C.
; 
Pike, Robert D.
Abstract
The title complex, [Ni(N3)(C3H9P)4]BF4, is a nearly perfect trigonal bipyramid with the azide group at an apical position. The metal-azide bond angle, Nil-- NlmN2, of 138.6(5) ° is the largest observed for a terminal azide ligand.
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1995
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Chemistry
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AZIDOTETRAKIS_TRIMETHYLPHOSPHINE_NICKEL_II__TETRAFLUOROBORATE.pdf
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Chemistry
DOI
https://doi.org/10.1107/S0108270194010553
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https://scholarworks.wm.edu/handle/internal/1144
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