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Slow collisions of hydride ion and deuteride ion with sodium, potassium and cesium

Wang, Yicheng
Abstract
The cross sections of charge transfer and electron detachment in collisions of H$\sp{-}$ and D$\sp{-}$ with Na, K and Cs have been measured for collision energies ranging from 3 to 300 eV. Both charge transfer and electron detachment are significant electron-loss mechanisms for H$\sp{-}$(D$\sp{-}$); both processes exhibit velocity-dependent isotope effects for H$\sp{-}$ and D$\sp{-}$. $\sigma\sb{\rm cg}$(E) displays high energetic thresholds for Na and K (about 20 eV for H$\sp{-}$ + Na and 40 eV for H$\sp{-}$ + K) yet no obvious one for Cs. $\sigma\sb{\rm e}$(E) does not depend on the target as much as $\sigma\sb{\rm ct}$(E) and displays near zero-energy thresholds. The relative importance of charge transfer as an electron-loss mechanism decreases as the mass of the alkali-metal increases.
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1987
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Physics
DOI
https://dx.doi.org/doi:10.21220/s2-r2fg-0r98
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