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Convenient Synthesis of Copper (I) Thiolates and Related Compounds
Nguyen, Lynda M. Dellinger, Megan E. Lee, Jeffrey T. Quinlan, Ronald A. Rheingold, Arnold L. Pike, Robert D.
Nguyen, Lynda M.
Dellinger, Megan E.
Lee, Jeffrey T.
Quinlan, Ronald A.
Rheingold, Arnold L.
Pike, Robert D.
Abstract
Copper (I) salts of various anions including thiolates, diethyl dithiocarbamate, diethyl dithiophosphate, trithiocyanurate, 1-cyano-3-methylisothiourea, 2-aminothiazole, and tetrakis(1-imidazolyl)borate are conveniently synthesized by reducing copper (II) sulfate in aqueous ammonia. The addition of phosphine ligands to several of the products is demonstrated, and the crystal structure of [Cu2(MBT)2(DPPE)3] · Et2O (MBT = 2-mercaptobenzothiazolate, DPPE = 1,2-bis(diphenylphosphino)ethane) is reported.
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2005-03-01
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Chemistry
DOI
https://doi.org/10.1016/j.ica.2004.11.030
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