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Iodobismuthate(III) and Iodobismuthate(III)/Iodocuprate(I) Complexes with Organic Ligands

Kelly, Andrew W.
; 
Wheaton, Amelia M.
; 
Nicholas, Aaron D.
; 
Barnes, Francis H.
; 
Patterson, Howard H.
; 
Pike, Robert D.
Abstract
Iodobismuthate(III) and iodobismuthate(III)/cuprate(I) complexes with chelating and bridging organic ligands are structurally characterized, including the first iodobismuthate(III) metal–organic polymers. BiIII/CuI clusters show ligand binding at copper. Diffuse reflectance spectra show UV/Vis absorptions, and DFT calculations suggest MLCT and metal–halide centered transitions.
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2017-10-01
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Chemistry
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Iodobismuthate_III__and_Iodobismuthate_III__iodocuprate_I__Complexes_with_Organic_Ligands.pdf
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Chemistry
DOI
https://doi.org/10.1002/ejic.201701052
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https://scholarworks.wm.edu/handle/internal/1167
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