Date Thesis Awarded

5-2017

Access Type

Honors Thesis -- Access Restricted On-Campus Only

Degree Name

Bachelors of Science (BS)

Department

Chemistry

Advisor

Christopher J. Abelt

Committee Members

Douglas D. Young

William R. McNamara

Mainak Patel

Abstract

Molecular sensors are molecules that interact with substances of interest and produce a detectable change. Therefore, their unique properties have been applied in various field. This paper aims to study whether structural changes are required for the molecular sensor 5-propionyl-1-dimethylaminonapthalene to reach its charge transfer excited state. After examining the solvatochromism, quantum yield, and hydrogen bond quenching data between 5-propionyl-1-dimethylaminonapthalene and 1-(1-methyl-1, 2, 3, 4-tetrahydronaptho[1, 8-bc] azepin-7-yl) propan-1-one, this paper concludes that 5-propionyl-1-dimethylaminonapthalene fluoresces through a planar ICT and the carbonyl group is sensitive to hydrogen bond quenching.

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