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Cubane Tetrameric Complexes of Copper(I) Chloride and Bromide with Triphenyl Phosphite

Pike, Robert D.
; 
Starnes, William H.
; 
Carpenter, Gene B.
Abstract
The crystal structures of tetra-/z3-chloro-tetrakis[(triphenyl phosphite-P)copper(I)], [CunC14(CI8HI503P)4], and tetra-#3-bromo-tetrakis [ (triphenyl phosphite-P) - copper(I)], [Cu4Br4(CI8H1503P)4], are described. Both have distorted 'cubane' CuaX4 cores. Distortion of the cubane structure is reflected in X--Cu--X angles > 90 ° and Cu--X--Cu angles < 90 °, and is more pronounced in the bromide complex.
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1999
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Chemistry
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Chemistry
DOI
https://doi.org/10.1107/S0108270198012451
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https://scholarworks.wm.edu/handle/internal/1143
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