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Bis{l-2,20-[1,10-(ethane-1,2-diyldinitrilo)- diethylidyne]diphenolato}bis[(benzoatojO)manganese(III)] dihydrate
Thampidas, V. S. Radhakrishnan, T. Pike, Robert D.
Thampidas, V. S.
Radhakrishnan, T.
Pike, Robert D.
Abstract
The title compound, [Mn2(C18H18N2O2)2Cl2], was synthesized by the reaction between manganese(II) o-chlorobenzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxyacetophenone. The centrosymmetric dimer contains two Jahn-Teller-distorted manganese(III) ions, each in an octahedral geometry, connected through two phenoxy bridges from two ligands.
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Date
2008-01-01
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Chemistry
DOI
https://doi.org/10.1107/S1600536808000226