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Semiclassical Model of Λ-doublet States in Diatomic Molecules
Kovalenko, Laurie J. Delos, John B.
Kovalenko, Laurie J.
Delos, John B.
Abstract
An intuitive picture of Λ-doubling in diatomic molecules is presented using a semiclassical theory. A common view of Λ-doubling as arising from electrons “lagging” behind the rotating internuclear axis is shown to be misleading; rather, the eigenfunctions are symmetric about the molecular axes and can be expressed as a superposition of pure nonrotating orbitals and travelling waves. These results are shown to be consistent with a full quantum treatment. We also examine, for the first time, time-dependent states, by monitoring expectation values of electronic- and nuclear-angular momenta. For low rotation frequency, the expectation value of the electronic-angular momentum locks onto the rotating internuclear axis, while for high rotation frequency it locks onto the space-fixed total-angular momentum axis. At intermediate frequencies is a complicated behavior.
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Date
1997
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American Institute of Physics
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Physics
DOI
https://doi.org/10.1063/1.474251