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Threaded Structure and Blue Luminescence of (CuCN)20(Piperazine)7
Pike, Robert D. deKrafft, Kathryn E. Ley, Amanda N. Tronic, Tristan A.
Pike, Robert D.
deKrafft, Kathryn E.
Ley, Amanda N.
Tronic, Tristan A.
Abstract
The structurally unique and highly luminescent 20 : 7 complex of CuCN with piperazine (Pip) was formed under aqueous conditions; its structure reveals two interpenetrated 2D sub-networks in 6 : 1 ratio: (CuCN)2(Pip) and (CuCN)8(Pip), the latter consisting of Cu18(CN)16(Pip)2 macrocycles.
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Date
2007-07-01
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Chemistry
DOI
https://doi.org/10.1039/B707582K