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Copper(I) Chloride Carbonyl Polymers
Wiles, Austin B. Pike, Robert D.
Wiles, Austin B.
Pike, Robert D.
Abstract
Addition of bridging diamine ligands to methanolic solutions of CuCl under a CO purge produces the polymeric complexes [(CuCl)2(CO)2(biL)] (biL = diazabicyclo[2.2.2]octane (DABCO), piperazine (Pip), N,N‘-dimethylpiperazine (DMP)). X-ray crystal structures of the three complexes reveal rhombic OC−Cu(μ-Cl)2Cu−CO bridged by biL. Unsaturated bridging ligands fail to produce carbonyl-bearing products.
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2006-05-01
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Chemistry
DOI
https://doi.org/10.1021/om0601504