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Reversible Luminescent Reaction of Amines with Copper(i) Cyanide
Ley, Amanda N. Dunaway, Lars E. Brewster, Timothy P. Dembo, Matthew D. Pike, Robert D.
Ley, Amanda N.
Dunaway, Lars E.
Brewster, Timothy P.
Dembo, Matthew D.
Pike, Robert D.
Abstract
Copper(I) cyanide exposed to various liquid or vapor-phase amines (L) at ambient temperature produces a variety of visible photoluminescence colors via reversible formation of amine adducts. The adducts show phase matches to authentic (CuCN)Ln, n = 0.75–2.0, produced by heating CuCN with liquid amine.
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Date
2010-07-01
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Chemistry
DOI
https://doi.org/10.1039/C002351E