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Poly[l-2-aminopyrazine-j2 N1 :N4 - l-cyanido-copper(I)]: A Three-dimensional Network From Laboratory Powder Diffraction Data

Pagola, Silvina
; 
Pike, Robert D.
; 
deKrafft, Kathryn
; 
Tronic, Tristan A.
Abstract
In the title compound, [Cu(CN)(C4H5N3)]n or [Cu(-CN)(-PyzNH2)]n (PyzNH2 is 2-aminopyrazine), the CuI center is tetrahedrally coordinated by two cyanide and two PyzNH2 ligands. The CuI-cyano links give rise to [Cu-CN] chains running along the c axis, which are bridged by bidentate PyzNH2 ligands. The three-dimensional framework can be described as being formed by two interpenetrated three-dimensional honeycomb-like networks, both made of 26-membered rings of composition [Cu6(-CN)2(-PyzNH2)4].
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2008-01-01
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Chemistry
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Chemistry
DOI
https://doi.org/10.1107/S010827010800231X
URI
https://scholarworks.wm.edu/handle/internal/1134
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