Document Type

Article

Department/Program

Chemistry

Pub Date

10-2017

Volume

2017

Issue

43

First Page

4990

Abstract

Iodobismuthate(III) and iodobismuthate(III)/cuprate(I) complexes with chelating and bridging organic ligands are structurally characterized, including the first iodobismuthate(III) metal–organic polymers. BiIII/CuI clusters show ligand binding at copper. Diffuse reflectance spectra show UV/Vis absorptions, and DFT calculations suggest MLCT and metal–halide centered transitions.

DOI

https://doi.org/10.1002/ejic.201701052

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