Date Awarded
2001
Document Type
Dissertation
Degree Name
Doctor of Philosophy (Ph.D.)
Department
Applied Science
Abstract
Multi Angle Laser Light Scattering (MALLS) and Frequency Dependent Electromagnetic Sensing (FDEMS) provide unique characterizations of polymer systems during cure and use-aging. This research illustrates how MALLS is an extremely accurate technique for absolute characterization of macromolecules, giving molecular weight and size information that other widely used and accepted techniques are incapable of measuring. Application of MALLS to monitoring the changing state of a polyamide-11 system in a water aging environment led to the discovery of an equilibrium molecular weight which is the result of two competing reactions, hydrolysis-degradation and a newly discovered recombination-polymerization reaction. The discovery of this recombination reaction creates the possibility of an indefinitely healthy polyamide-11 polymer system. FDEMS successfully monitored changing water content and degree of cure of a moisture-curing adhesive polymer. The data show potential for total in situ cure characterization by FDEMS, including in situ determinations of moisture diffusion rates during a polymer cure in the adhesive bondline.
DOI
https://dx.doi.org/doi:10.21220/s2-kzzv-e460
Rights
© The Author
Recommended Citation
Meyer, Andrew Orschel, "Characterizing and monitoring changes in state of polymers during cure and use -aging" (2001). Dissertations, Theses, and Masters Projects. William & Mary. Paper 1539623376.
https://dx.doi.org/doi:10.21220/s2-kzzv-e460
