Tetraethylammonium tri-l-phenolatobis [Tricarbonylmanganate(I)]

Authors

Timothy J. McNeese
Robert D. Pike, William & MaryFollow

Document Type

Article

Department/Program

Chemistry

Journal Title

Acta Crystallographica Section E

Pub Date

2011

Volume

E67

Abstract

The title compound, (C8H20N)[Mn2(C6H5O)3(CO)6], was synthesized from [Mn(CO)3(CH3CN)3]BF4 and (C8H20N)(OC6H5). The binuclear anion exhibits a pseudo-threefold symmetry and contains two six-coordinate Mn atoms. Each metal atom is coordinated by three facially oriented CO ligands and three doubly-bridging phenolate ligands. The average O-Mn-O bond angle is 74.9 (7)° in the Mn2O3 metal-phenolate dimeric core, yielding a distorted octa­hedron for each metal.

Recommended Citation

McNeese, Timothy J. and Pike, Robert D., Tetraethylammonium tri-l-phenolatobis [Tricarbonylmanganate(I)] (2011). Acta Crystallographica Section E, E67.
https://doi.org/10.1107/S1600536811029266

DOI

https://doi.org/10.1107/S1600536811029266