"A Merged Aldol Condensation, Alkene Isomerization, Cycloaddition/Cyclo" by Jill B. Williamson, Emily R. Smith et al.
 

Document Type

Article

Department/Program

Chemistry

Journal Title

SYNLETT

Pub Date

7-2017

Volume

28

Issue

10

Abstract

A domino reaction sequence has been evaluated that begins with union of novel dihydrooxazinone precursors with 2-alkynyl-substituted benzaldehyde components through aldol condensation. Ensuing operations, including alkene isomerization, Diels-Alder, and retrograde Diels-Alder with loss of CO2 occurs in the same reaction vessel to provide polysubstituted tricyclic pyridine products.

DOI

10.1055/s-0036-1588729

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