Aqua {2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(3-nitrobenzoato)manganese(III)

Authors

V. S. Thampidas
T. Radhakrishnan
Robert D. Pike, William & MaryFollow

Document Type

Article

Department/Program

Chemistry

Journal Title

Acta Crystallographica Section E

Pub Date

2008

Volume

E64

Abstract

The title compound, [Mn(C16H14N2O2)(C7H4NO4)(H2O)], is a Jahn-Teller-distorted manganese(III) monomer with an octa­hedral geometry. The tetra­dentate Schiff base accommodates the MnIII ion at the centre of a nearly planar square. The axial positions are occupied by a monodentate carboxyl­ate group and a water mol­ecule. Adjacent monomers inter­act through hydrogen bonding between the noncoordinated C=O group of the carboxyl­ate and the coordinated water mol­ecule to produce chains extending parallel to the b axis.

Recommended Citation

Thampidas, V. S.; Radhakrishnan, T.; and Pike, Robert D., Aqua {2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(3-nitrobenzoato)manganese(III) (2008). Acta Crystallographica Section E, E64.
https://doi.org/10.1107/S1600536808019715

DOI

https://doi.org/10.1107/S1600536808019715