Poly[l-2-aminopyrazine-j2 N1 :N4 - l-cyanido-copper(I)]: A Three-dimensional Network From Laboratory Powder Diffraction Data

Authors

Silvina Pagola
Robert D. Pike, William & MaryFollow
Kathryn deKrafft
Tristan A. Tronic

Document Type

Article

Department/Program

Chemistry

Journal Title

Acta Crystallographica Section C

Pub Date

2008

Volume

C64

Abstract

In the title compound, [Cu(CN)(C4H5N3)]n or [Cu(-CN)(-PyzNH2)]n (PyzNH2 is 2-amino­pyrazine), the CuI center is tetra­hedrally coordinated by two cyanide and two PyzNH2 ligands. The CuI-cyano links give rise to [Cu-CN] chains running along the c axis, which are bridged by bidentate PyzNH2 ligands. The three-dimensional framework can be described as being formed by two inter­penetrated three-dimensional honeycomb-like networks, both made of 26-membered rings of composition [Cu6(-CN)2(-PyzNH2)4].

Recommended Citation

Pagola, Silvina; Pike, Robert D.; deKrafft, Kathryn; and Tronic, Tristan A., Poly[l-2-aminopyrazine-j2 N1 :N4 - l-cyanido-copper(I)]: A Three-dimensional Network From Laboratory Powder Diffraction Data (2008). Acta Crystallographica Section C, C64.
https://doi.org/10.1107/S010827010800231X

DOI

https://doi.org/10.1107/S010827010800231X