Document Type
Article
Department/Program
Chemistry
Journal Title
Acta Crystallographica Section C
Pub Date
1995
Volume
C51
First Page
595
Abstract
The title complex, [Ni(N3)(C3H9P)4]BF4, is a nearly perfect trigonal bipyramid with the azide group at an apical position. The metal-azide bond angle, Nil-- NlmN2, of 138.6(5) ° is the largest observed for a terminal azide ligand.
Recommended Citation
Carson, Caryn C. and Pike, Robert D., Azidotetrakis(trimethylphosphine)nickel(II) Tetrafluoroborate (1995). Acta Crystallographica Section C, C51, 595-598.
https://doi.org/10.1107/S0108270194010553
DOI
https://doi.org/10.1107/S0108270194010553