Copper(I) Chloride Carbonyl Polymers

Authors

Austin B. Wiles
Robert D. Pike, William & MaryFollow

Document Type

Article

Department/Program

Chemistry

Journal Title

Organometallics

Pub Date

5-2006

Volume

25

Issue

13

First Page

3282

Abstract

Addition of bridging diamine ligands to methanolic solutions of CuCl under a CO purge produces the polymeric complexes [(CuCl)2(CO)2(biL)] (biL = diazabicyclo[2.2.2]octane (DABCO), piperazine (Pip), N,N‘-dimethylpiperazine (DMP)). X-ray crystal structures of the three complexes reveal rhombic OC−Cu(μ-Cl)2Cu−CO bridged by biL. Unsaturated bridging ligands fail to produce carbonyl-bearing products.

Recommended Citation

Wiles, Austin B. and Pike, Robert D., Copper(I) Chloride Carbonyl Polymers (2006). Organometallics, 25(13), 3282-3285.
https://doi.org/10.1021/om0601504

DOI

https://doi.org/10.1021/om0601504