The Effect of Functionalized versus Unmodified Graphene Oxide on Polyimide Nanocomposite Properties
Date Thesis Awarded
Honors Thesis -- Access Restricted On-Campus Only
Bachelors of Science (BS)
Abstract Polyimides are a commercially useful material, typically used in air and space applications due to high heat resistance, impressive mechanical strength, and self-extinguishing properties. In recent years, graphene has come of interest in the material science world. However, the pristine, carbon-honeycomb allotrope is extremely hydrophobic, chemically unreactive and it is therefore difficult, if not impossible, to disperse graphene nanoparticles as single nanosheets into polar solvents used typically used for polymerization and synthesis. Focus has shifted to graphene oxide (GO); the honeycomb structure of graphene with oxygen-containing functional groups on the surface. Incorporation of GO into polyimides is shown to improve mechanical properties, increase gas barrier properties and to increase water solvent resistance along with other solvents. Functionalization of GO sheets with monomer components of the chosen polymer results in further improvements of these properties. Here we demonstrate that tailoring of GO to be compatible with polyimide resins is a valuable technique in enhancing GO-polymer composite properties.
Hudson-Smith, Natalie V., "The Effect of Functionalized versus Unmodified Graphene Oxide on Polyimide Nanocomposite Properties" (2015). Undergraduate Honors Theses. William & Mary. Paper 142.
Creative Commons License
This work is licensed under a Creative Commons Attribution-Noncommercial-No Derivative Works 4.0 License.
On-Campus Access Only